MELANTERITE

    Class : Sulfates, chromates, molybdates
    Subclass : Hydrated sulfates
    Crystal system : Monoclinic
    Chemistry : FeSO4 7H2O
    Rarity : Common


Melanterite is a hydrated iron sulfate that forms by alteration of pyrite and marcasite under very acidic pH conditions. It is a very fragile secondary mineral, difficult to preserve outside the acidic humidity of the mine galleries where it was born, due to its great solubility and its ability to dehydrate : in a dry atmosphere, melanterite dehydrates and transforms into an iron sulfate with five water molecules, siderotile, then oxidizes into copiapite and other iron sulfates. Melanterite is also known in lignite layers, often rich in iron sulfides. Its name comes from the Greek melanteria, a term designating the process of obtaining copper metal by cementation. Melanterite most often forms fibers, sometimes capillary, assembled into mats, encrustations or efflorescences, generally colorless to greenish. The concretions or stalactites, as well as the rare isometric or short prismatic crystals, have a green to emerald green color changing to blue-green. This blue-green hue generally results from the replacement of iron by copper (up to 19% CuO) : this is the pisanite variety. Melanterite is used in the manufacture of fertilizers, certain inks, disinfectants and is used in water purification systems. It is also used to a limited extent as a pigment and contributes to the conservation of wood.

Main photo : Melanterite from Aljustrel Mine, Portugal © Rui Nunes

Melanterite stalactites from Johan Hell Mine, Romania © Pawel Zochowski
Melanterite from Aljustrel Mine, Portugal © Rui Nunes
Melanterite from Lousal Mine, Portugal © António Manuel Ináçio Martins
Melanterite from St-Laurent-le-Minier, Gard, France © Yannick Vessely

Melanterite in the World

Melanterite stalagmites several meters high and sometimes metric in diameter, and exceptional crystals (metric plates of crystals individually reaching up to 6 cm across) were formed in the underground mining chambers of Rio Tinto (Spain) since mining work stopped. Melanterite, often accompanied by its copper variety, pisanite, is associated with other complex iron and copper sulfates (voltaite, coquimbite, copiapite, etc...). The mining chambers of the neighboring La Zarca mine provided specimens of close quality. Melanterite is present in neoformation in many American mines such as Butte (Montana), Bingham (Utah), etc...

Melanterite in France

In France, melanterite is known in decimetric stalactites in the Salsigne gold mine (Aude). It is also known in St-Laurent-le-Minier (Gard), Chessy (Rhône), as well as in many other mines.

Twinning

No twin known for this mineral species.

Fakes and treatments

No fakes recorded for this mineral species.



Hardness : 2
Density : 1.89
Fracture : Conchoidal
Streak : White


TP : Translucent to opaque
RI : 1.470 to 1.486
Birefringence : 0.016
Optical character : Biaxial +
Pleochroism : None
Fluorescence : None


Solubility : Water

Magnetism : NoneRadioactivity : None

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