PYROCHLORE

    Class : Oxides and hydroxides
    Subclass : Oxides
    Crystal system : Cubic
    Chemistry : (Na,Ca)2Nb2O6(OH,F)
    Rarity : Fairly common


Pyrochlore is a complex oxide of niobium which forms a continuous series with microlite, a mineral in which tantalum replaces niobium. The pyrochlore group includes complex oxides with the general formula A2B2O6(O,OH,F), with A = Ba, Bi, Ca, Ce, Cs, K, Na, Pb, Sb, Sn, Sr, Th, U, Y , Zr and B = Fe, Nb, Sn, Ta, Ti, W. Varieties rich in radioactive elements are commonly metamict and admit significant quantities of water. By uranium enrichment, we move on to betafite. Pyrochlore is found in granitic pegmatites and greisens, but especially in the pegmatites of nepheline syenites as well as in carbonatites. It is a resistant mineral that preserves well in alluvial deposits. Its name comes from the Greek pûr (fire) and khlôros (green) because the mineral turns green when heated. Pyrochlore is frequently crystallized, most often in octahedra that very rarely exceed 5 cm, but can adopt much more complex shapes by combination with the rhombododecahedron. The fracture is conchoidal to irregular, the color black to black-brown or dark red-brown, rarely red to vermilion. It is a mineral which is sometimes exploited as a rare earth and niobium ore : the alluvium deriving from the erosion of nepheline syenite massifs or alkaline complexes represent the main world reserves of niobium and tantalum.

Main photo : Pyrochlore from Vishnevye Mountains, Chelyabinsk, Russia © Knut Eldjarn

Pyrochlore from Talarskij, Russia © Rob Lavinsky
14 cm pyrochlore from Talarskij, Russia © Rob Lavinsky
Pumpellyite de Costa Sopramare, Ligurie, Italie © Gianfranco Ciccolini
Pyrochlore from In den Dellen quarries, Eifel, Germany © Volker Heck
Pyrochlore from Água de Pau Volcano, São Miguel, Azores, Portugal © Gianfranco Ciccolini

Pyrochlore in the World

The largest pyrochlore crystals come from Russia : Vishnevye Gor, near Miass (Urals), with shiny dark brown octahedrons reaching 15 mm, and Talarskij which gave octahedra of 14 cm, the largest known. Magnificent crystals have also been extracted from the carbonatite of Oka, near Montreal (Quebec, Canada), and the syenitic pegmatites of Pike Peak (Colorado). Pyrochlor is also common in the syenite massifs of southern Norway, near Larvik and in the nepheline syenites of the Los Islands (Guinea).

Pyrochlore in France

In France, pyrochlore is known in the Monts d'Ambazac and Compreignac (Haute-Vienne), in Echassières (Allier) and in Fitou near Narbonne (Aude).

Twinning

No twins known for this mineral species.

Fakes and treatments

No fakes listed for this mineral species.



Hardness : 5
Density : 4
Fracture : Irregular to cocnhoidal
Streak : Yellow to brown


TP : Translucent to opaque
RI : 1.960 to 2.010
Birefringence : 0
Optical character : None
Pleochroism : None
Fluorescence : None


Solubility : Sulfuric acid

Magnetism : NoneRadioactivity : None