TRIPHYLITE

    Class : Phosphates, arsenates, vanadates
    Subclass : Anhydrous phosphates
    Crystal system : Orthorhombic
    Chemistry : LiFePO4
    Rarity : Fairly common


Triphylite is a primary iron and lithium phosphate found exclusively in sodolithic granitic pegmatites and is probably the most common phosphate in these formations. It forms a continuous series with lithiophilite, its manganese counterpart. Atmospheric and hydrothermal alteration of triphylite is at the origin of the formation of numerous secondary phosphates (ferrisicklerite, heterosite and purpurite when lithium is eliminated). This transformation gives the mineral a black surface color that propagates along the cleavages, drawing a grid pattern. Its name comes from the Greek treis (three) and phûlon (family), because this mineral contains three cations. Blue-gray to greenish-gray in color, becoming brown by alteration, generally translucent to opaque, triphylite most often forms cleavable to compact masses that can reach considerable dimensions (up to 5 meters); well-individualized crystals, prismatic with pseudohexagonal section, are very rare.

Main photo : Triphylite from Chandlers Mill Quarry, New Hampshire, USA © Rock Currier

Triphylite in the World

Triphylite is common in all American pegmatites (Maine, Massachusetts, New Hampshire), and especially in South Dakota (Custer, Keystone), in metric masses and centimetric crystals of good quality. The Brazilian pegmatite of Sapucaia (Minas Gerais) has also provided large masses. Triphylite is known in several pegmatites in Europe, notably in Varuträsk (Sweden) and Hagendorf (Germany).

Right photo : Blue triphylite fromTriphylite from Chandlers Mill Quarry, New Hampshire, USA © Kelly Nash

Triphylite in France

In France, the sodolithic pegmatites of the Ambazac mountains in Limousin (Saint-Sylvestre, Chanteloube) have given cleavable masses that are sometimes decimetric but often strongly altered. It is also reported in the pegmatites of Collioure (Pyrénées-Orientales).

Twinning

No twin known for this mineral species.

Fakes and treatments

No fakes listed for this mineral species.



Hardness : 4
Density : 3.42 to 3.58
Fracture : Irregular
Streak : Gray-white


TP : Translucent
RI : 1.685 to 1.720
Birefringence : 0.008
Optical character : Biaxial -
Pleochroism : None
Fluorescence : None


Solubility : Acids

Magnetism : NoneRadioactivity : None