CRISTOBALITE

    Class : Silicates
    Subclass : Tectosilicates
    Crystal system : Tetragonal
    Chemistry : SiO2
    Rarity : Common


Cristobalite is one of the polymorphs of silica, like stishovite, coesite, trydimite and quartz. It exists in two forms : a high temperature, cubic, and a low temperature, pseudocubic tetragonal. It is a mineral in volcanic rocks that is found in the vacuoles of rhyolites, trachytes and andesites but also in meteorite impact glasses. It owes its name to its location of discovery : Cerro San Cristobal in Mexico. High temperature cristobalite occurs in small translucent octahedra, white to grayish in color, sometimes twinned on {111} ; low temperature forms build cryptocrystalline aggregates, sometimes fibrous or spheroidal which incorporate certain opals (opal-C and opal-CT), or by devitrification integrate certain volcanic glasses or impact glasses. A small part of French silica production is supplied by cristobalite and tridymite. However, these are synthetic minerals obtained by calcination of flint pebbles: between 900°C and 1100°C, we obtain a product containing 55% tridymite and 45% cristobalite, and between 1450°C and 1600°C , the product contains between 80 and 90% cristobalite. It is then used as an extra-white filler for prestigious structural concretes, and as an extra-white filler in paints.

Main photo : Cristobalite from Bellerberg volcano, Germany © Edgard Müller

Cristobalite spherules in Egyptian lybic glass
36.55ct faceted Cristobalite Quartz from Brazil
Obsidian cabochon with cristobalite and tridymite flakes from the USA
Cristobalite from Caspar Quarry, Germany © Fred Kruijen

Cristobalite in the World

The most beautiful cristobalite crystals are 4 mm octahedra found in the andesites of Cerro San Cristobal (Pachuca, Mexico). Good crystals have also been discovered in Hungary (Sarospatak), in the Czech Republic (Nezdenice). The lavas of Hyderabad (India) have yielded magnificent octahedra, sometimes twinned, implanted on mordenite. By devitrification of obsidian it is the origin of flake obsidian which is found in California and Japan. The most spectacular specimens are those from Futo and Goroyama (Honshû, Japan) where the spherules reach 10 cm in diameter.

Cristobalite in France

In France, cristobalite is known in the trachyte of Puy de Cliersou in the Chaîne des Puys (Puy-de-Dôme) where it constitutes 10% of the rock.

Twinning

Cristobalite sometimes twins on {111}.

Fakes and treatments

No fakes listed for this mineral species, but easy to confuse with hematite without chemical analysis...



Hardness : 6 to 7
Density : 2.32 to 2.36
Fracture : Conchoidal
Streak : White


TP : Translucent to transparent
RI : 1.484 to 1.487
Birefringence : 0.003
Optical character : Uniaxial -
Pleochroism : None
Fluorescence : None


Solubility : Hydrofluoric acid


Magnetism : None
Radioactivity : None