NATROJAROSITE

    Class : Sulfates, chromates, molybdates
    Subclass : Anhydrous sulfates
    Crystal system : Trigonal
    Chemistry : NaFe3(SO4)2(OH)6
    Rarity : Rare to uncommon


Natrojarosite is a double sulfate of sodium and iron. It is a secondary mineral formed by alteration of iron sulfides, mainly in arid climates. It is frequently associated with jarosite, with which however there does not seem to be a continuous solid solution. Natrojarosite, like jarosite, results from precipitation from "natural" sulfuric acid, formed by reaction of surface water with iron sulfides. By changing environmental conditions (temperature, pH, redox potential, etc...), natrojarosite and jarosite are easily hydrolyzed into ferric hydroxides (goethite and limonite). Its name derives from its chemical composition : from the Latin natrium (sodium), and its chemical analogy with jarosite. Natrojarosite usually occurs in encrustations, in compact granular, concretionary or earthy masses, rarely in very small, flattened rhombohedral crystals. It is ocher-yellow to brownish orange in color, sometimes pale orange.

Main photo : Natrojarosite from Gilbert Mining District, Nevada, USA © Douglas Merson

Natrojarosite from Hangstberg, Austria © Christian Auer
Natrojarosite from Kamariza Mines, Lavrion, Greece © Douglas Merson
Natrojarosite from Esperanza Mine, Lavrion, Greece © Uwe Kolitsch - SEM picture
Natrojarosite from Jas Roux, Hautes-Alpes, France © Vincent Bourgoin

Natrojarosite in the World

Natrojarosite is a discreet mineral and is most likely more common than generally recognized. Good specimens come from the Laurion (Greece), Tonopah (Nevada) and Milgun Station (Australia) mines.

Natrojarosite in France

In France, natrojarosite is known at Echassières (Allier), at the La Grange Mine near Ussel (Corrèze) and at Jas Roux (Hautes-Alpes).

Twinning

No twins known for this mineral species.

Fakes and treatments

No fakes recorded for this mineral species.



Hardness : 2.5 to 3.5
Density : 3.18
Fracture : Conchoidal
Streak : Pale yellow


TP : Translucent to transparent
RI : 1,750 to 1,830
Birefringence : 0.080
Optical character : Uniaxial -
Pleochroism : Visible
Fluorescence : None


Solubility : Hydrochloric acid

Magnetism : NoneRadioactivity : None

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